Repositório Institucional da Universidade Federal de Sergipe
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A new example of intramolecular C—H...Ni anagostic interactions: synthesis, crystal structure and Hirshfeld analysis of cis-bis[4-methyl-2- (1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-j2 N1 ,S]nickel(II) dimethylformamide monosolvate
The reaction of NiII acetate tetrahydrate with 4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide in a 2:1 molar ratio and recrystallization from dimethylformamide yielded the title compound, [Ni(C12H14N3S)2]C3H7NO. The ligands act as monoanionic 2 N1 ,S-donors, forming
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