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Hydrogen isotope mixing entropy in ammonia clusters

Hansen, Klavs et al.
arXiv (All) · Papers
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atomic-and-molecular-clusters
Measured evaporation branching ratios of partially deuterated isotopologues of protonated ammonia clusters (NH$_3$)$_N$ H$^+$ ($N \geq 8$) show ratios that depend only on the clusters' deuterium mole fraction. This demonstrates randomly distributed protium and deuterium in the molecules and can be u
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