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The seeming lack of CF...HO intramolecular hydrogen bonds in linear aliphatic fluoroalcohols in solution
No CF⋯HO intramolecular hydrogen bonds (IHBs) in 2-fluoroethanol, 3-fluoropropanol and 4-fluorobutanol can be detected experimentally in solution by NMR and infrared spectroscopies. According to ab initio (MP2/aug-cc-pVDZ) and DFT calculations (B3LYP), a CF⋯HO IHB has no influence on the conformatio
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