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On-Surface Heptagon Contraction Enables Rearrangement Driven Selective C–C Coupling
biophysicsbiotechnologyevolutionary-biologygeneticsinorganic-chemistrymicrobiologymolecular-biologyphysiology
On-surface synthesis commonly relies on preinstalled C–X activation sites to initiate intermolecular coupling, which limits reactivity to precursor-encoded positions and can be impractical for frameworks that are difficult to halogenate in solution. Here, we report a rearrangement-driven coupling re
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