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Dynamic Metal-Semiconductor Electrical Interfaces in Model Cu|ZnO Hydrogenation Catalyst Structures
Cu/ZnO/Al 2 O 3 catalysts are commonly used for methanol synthesis, yet the chemical state of the Cu|ZnO interface remains debated. We probe Cu|ZnO interfacial chemistry by measuring junction electrical characteristics under N 2 , CO 2 and gas mixtures from 50 to 250 °C and up to 10 bar(a). The pris
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