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Engineering highly reduced molybdenum polyoxometalates via the incorporation of d and f block metal ions
The assembly of nanoscale polyoxometalate (POM) clusters has been dominated by the highly reduced icosahedral {Mo 132 } ‘browns’ and the toroidal {Mo 154 } ‘blues’ which are 45% and 18% reduced respectively. We hypothesised that there is space for a greater diversity of structures in this immediate
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