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Non-Precious Metals Catalyze Formal [4+2] Cycloaddition Reactions of 1,2-Diazines and Siloxyalkynes under Ambient Conditions
Copper(I) and nickel(0) complexes catalyze the formal [4 + 2] cycloaddition reactions of 1,2-diazines and siloxyalkynes, a reaction hitherto best catalyzed by silver salts. These catalysts based on earth abundant metals are not only competent, but the copper catalyst, in particular, promotes cycload
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