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Harnessing Biology’s Leviathan: Ribosomal Catalysis of Unnatural Bonds and Chemo-Ribosomal Methods for the Synthesis of Atropisomeric and Macrocyclic Peptides
The ribosome is the most complex molecular machine known to man. It is an ancient behemoth, a twisted megadalton mass of RNA and protein, whose molecular motions underly the translation of the genetic code into language of proteins. Like a leviathan, that great mythological sea monster, the ribosome
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