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Reference-Measure Freedom of the Effective Hamiltonian: From Stochastic Thermodynamics to the Macroscopic Limit

Okamoto, Ryuichi
arXiv (All) · Papers
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soft-condensed-matterstatistical-mechanics
The effective Hamiltonian (EH), also referred to as the potential of mean force or free-energy landscape, is widely used to describe equilibrium properties and slow dynamics in chemical and softmatter systems. However, the conventional EH has been argued to be ill-defined because it does not transfo
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