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Amplification of Lanthanide f‑Orbital Differences by Redox Noninnocent Semiquinone Binding

Fiszbein, DavidJ et al.
eScholarship · Papers
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A deeper understanding of the electronic structure of the lanthanides (Ln) is essential to harness their technological applications and enable responsible recovery/separation. Here, an isostructural series of tris(3,5-dimethyl-1-pyrazolyl)borate (Tp*)-supported LnIII adducts of a redox noninnocent 3
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