HAL (France)
open access
Acetoxy-Peroxyacetals: A Peroxycarbenium Precursor for the Synthesis of Hydroperoxides and Endoperoxides
Herein is examined the reactivity of acetoxy-peroxyacetals as a new source of acyclic peroxycarbenium species. Their reactivity was explored with Sc(OTf)3, a mild Lewis acid that promotes peroxycarbenium species. The resilience of tert-butyldimethylsilyl group on peroxyl function was found superior
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