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Photoexcited Palladium-Catalyzed Defluorinative 1,2-Functional-Group Migration of Allylic Alcohols
Interception of aryldifluoromethyl radicals by unactivated alkenes is typically limited to 1,2-difunctionalization. We report a photoexcited palladium-catalyzed defluoroalkylative rearrangement that combines selective monodefluorination of trifluoromethylarenes, radical addition, local 1,2-migration
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