HAL (France)
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Preferential Reduction of 2-Phenylpyridine under D <sub>2</sub> : Palladium Nanoparticles Stabilized by <i>N</i> -Heterocyclic Carbenes Prefer D <sub>2</sub> to H <sub>2</sub>
Late-stage hydrogen isotope exchange and dearomatization reactions under D 2 have recently been used for preparing labeled compounds using metal nanoparticle catalysts. In the case of dearomatization, lower rates are usually observed under D 2 compared to H 2 as a result of a kinetic isotope effect.
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