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cross-[B<sub>20</sub>H<sub>18</sub>]<sup>2–</sup> in Copper(I), Silver(I), and Cadmium(II) Complexation: Formation of [a<sup>2</sup>‑B<sub>20</sub>H<sub>18</sub>]<sup>4–</sup> and [B<sub>20</sub>H<sub>16</sub>]<sup>4–</sup> Tetraanions
The cross-[B20H18]2– anion, a synthetic challenge for decades, is introduced into coordination chemistry for the first time. Contrary to the well-behaved trans and iso isomers, the cross-[B20H18]2– exhibits
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