HAL (France)
open access
Iridium‐Photocatalyzed Deoxygenation of Sulfoxides: Competing Oxidative and Reductive Pathways for Thioether Synthesis
ABSTRACT The deoxygenation of sulfoxides to thioethers is a synthetically valuable transformation, given the ubiquity of thioether motifs in pharmaceuticals, materials, and natural products. However, traditional methods often rely on harsh conditions, stoichiometric reagents, or oxophilic additives,
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