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Agostic Hydridoborate Complexes as Masked Coinage‐Metal Hydrides: Hydride Migration Between Boron and Gold Unlocks CO2 Reactivity

Balakrishna Peddi et al.
HAL (France) · Papers
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boroncarbon-dioxidecatalysisdft
ABSTRACT Hydride addition to diphosphine‐borane (DPB) coinage‐metal complexes affords an unprecedented series of Cu(I), Ag(I), and Au(I) hydridoborate complexes 2‐M featuring bridging B–H···M interactions. Combined multinuclear NMR, IR, single‐crystal x‐ray diffraction, and DFT studies reveal the pr
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