HAL (France)
open access
Synthesis and Structures of Novel Chiral Cyclic Hypervalent Iodine(III) Reagents for Metal‐Free Ligand‐Transfer Reactions
ABSTRACT The preparation of novel chiral λ 3 ‐iodane reagents bearing transferable halogen‐, oxygen‐ or carbon‐based ligands is described. Among these hypervalent iodine(III)‐based compounds are (i) the first chiral bis(cyano‐λ 3 ‐iodane), whose bis(benziodazolone) structure is derived from an enant
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