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Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule
A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- A nd dodecanucelar zirc
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