HAL (France)
open access
Entropic Control of Ethylene and Acetylene Uptake in Silicon-Functionalized Ionic Liquids? An Experimental and Molecular Dynamics Study
Abstract Distinguishing and rationalizing the physical absorption of small hydrocarbon gases is inherently challenging due to their nonpolar character. Similar interaction energetics obscure the molecular origin of solubility trends. Herein we combine isochoric saturation measurements and polarizabl
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