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Why Ammoniated Lithium Borohydrides Liquefy and Resolidify?

Wang, Qian et al.
arXiv (All) · Papers
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materials-science
Ammonia (NH$_3$) absorption drives LiBH$_4\cdot x$NH$_3$ through a re-entrant ``solid--liquid--solid'' transition: LiBH$_4\cdot$NH$_3$ is a well-defined solid ammoniate, compositions near LiBH$_4\cdot 2$NH$_3$ are liquid-like or partially liquefied, whereas LiBH$_4\cdot 3$NH$_3$ returns to a more ri
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