HAL (France)
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Mechanistic Insights into C(sp 2 )−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes
Abstract A new family of phosphine‐ligated dicyanoarylgold(III) complexes has been prepared and their reactivity towards reductive elimination has been studied in detail. Both, a highly positive entropy of activation and a primary 12/13 C KIE suggest a late concerted transition state while Hammett a
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