HAL (France)
open access
Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation
Abstract A catalytic method to synthesize a broad array of cyclometalated (C^N)gold(III) complexes is reported here. An unprecedented Rh‐to‐Au III transmetalation allows the facile transfer of (C^N) ligands between these two metals in a redox‐neutral process. The reaction employs commercially availa
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