HAL (France)
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Kinetic and Product Study of the S‐oxidation vs HAT Chemoselectivity in Reactions Promoted by Nonheme Iron(IV)‐oxo Complex/NHPI Mediator System
Abstract The chemoselectivity between S‐oxidation and hydrogen atom transfer (HAT) from C−H bonds has been investigated in the oxidations of a series of aryl sulfides, alkyl aromatic compounds and benzylic alcohols promoted by the iron(IV)‐oxo complex [(N4Py)Fe IV (O)] 2+ (N4Py: N,N ‐bis(2‐pyridylme
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