HAL (France)
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Deciphering the Role of Crown‐ether Receptor Orientation in C‐H Oxidation Catalyzed by Supramolecular Nonheme Fe IV (O) Complexes
Abstract The outstanding efficiency and selectivity of enzymatic reactions, such as C−H oxidation by nonheme iron oxygenases, stems from a precise control of substrate positioning inside the active site. The resulting proximity between a specific moiety (a certain C−H bond) and the reactant (a Fe IV
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