HAL (France)
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Transient Induction of Chirality from an Activated Carboxylic Acid to a Zinc Complex
Abstract Enantiomerically pure activated carboxylic acids (ACAs), ( R )‐ and ( S )‐2‐cyano‐2‐phenylpropanoic acids, are exploited to program the induction of chirality onto a zinc metal complex over time. NMR analysis shows that binding of the enantiopure ACA conjugate base to the Zn 2+ center break
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