HAL (France)
open access
Controlled Dealkylation of Alkyl Esters With Halide Salts and Application in Tandem‐Catalyzed Protodecarboxylation of Organic Formates
The selective cleavage of the C–O bond of unactivated alkyl esters remains a major challenge to use them as C(sp3)‐electrophiles in cross‐coupling chemistry. Here, we report a systematic study on the dealkylation of alkyl formates using iodide salts, revealing the pivotal role of the Lewi
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