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First Evidence of Au‐CH 3 Bonding in Superatomic Au 13 Clusters
Abstract Chemical reduction of a dinuclear [(di‐NHC)Au 2 Cl 2 (di‐NHC)] complex (NHC=imidazol‐2‐ylidene), using excess NaBH 4 as reducing agent in presence of dichloromethane (DCM) as solvent, provides a molecular cluster with formula [Au 13 (di‐NHC) 5 (CH 3 ) 2 ]Cl 3 , exhibiting covalent bonds bet
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