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Diiron µ2-N2 complexes in bimetallic, four-fold bond activations of SiH4 to produce µ2-silicide complexes
Fe(0) dinitrogen complexes [SiP3 R]Fe-N[triple bond, length as m-dash]N-Fe[SiP3 R] (1-R; [SiP3 R] = PhSi(CH2PR2)3; R = i Pr, Ph) are accessed by one- or two-electron reduction of Fe(i) and Fe(ii) chloride complexes [SiP3 i Pr]FeCl or κ2-[SiP3 R]FeCl2 (R = i Pr, Ph), respectively, and fully character
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