HAL (France)
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Imidazole and Imidazolate Iron Complexes:\, On the Way for Tuning 3D-Structural Characteristics and Reactivity. Redox Interconversions Controlled by Protonation State
X-ray structures for six Fe(II) and Fe(III) complexes from two closely heptadentate N-tripodal ligands, L1H3 = tris[(imidazol-4-yl)-3-aza-3-butenyl]amine and L2H3 = tris[(imidazol-2-yl)-3-aza-3-butenyl]amine, are described:\, three complexes in the L1 series (namely, [Fe(II)(L1H3)]2+ and [Fe(III)(L1
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