HAL (France)
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Realization of Self-Terminating Underpotential Electropolymerization by Strong Supramolecular Monomer-Electrode Interaction
In this report, we show that electropolymerization of 3,4-ethylenedioxythiophene (EDOT) can take place at 0.4 V, a voltage far lower than the conventionally employed voltage of 1.0 V, in a self-terminating manner, when Au is employed as a working electrode. DFT calculations revealed that the highest
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