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Precursor stoichiometry controls dopant structure, defect chemistry, and valence in Mn-doped ZnGa$_2$O$_4$ nanocrystals
The luminescence of doped nanocrystals is usually optimised through the activator; here we show that the host cation ratio is an equally decisive, and largely overlooked, design variable. Mn-doped ZnGa$_2$O$_4$ nanocrystals (Mn:Zn = $4\times10^{-4}$) were grown hydrothermally at nominal Zn/Ga ratios
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