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Hydrogen-Bond Density Drives the Order-Disorder Phase Transition from Orientational to Vibrational in Polyalcohol Plastic Crystals

Sanuy, Ares et al.
arXiv (All) · Papers
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materials-science
Neopentane-derived plastic crystals undergo order-disorder phase transitions accompanied by exceptionally large entropy changes, making them attractive solid-state materials for thermal energy storage and barocaloric cooling. Yet it remains unclear whether the microscopic nature of this entropy chan
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