HAL (France)
open access
Aqueous Catalyst-Free Derivatization of Polysaccharides with Epoxides at Neutral pH
We report a simple revisited route to derivatize polysaccharides with molecular epoxides or epoxide-functionalized macromolecules in water at neutral pH, without a catalyst. Exploiting model reactions on monosaccharide derivatives, we show that the catalyst-free grafting of epoxides is feasible when
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