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Multimodal Nanoscale Mapping of Local Structure and CO2 Adsorption in Metal–Organic Frameworks
Diamine functionalization of the metal-organic framework Mg2(dobpdc) (dobpdc4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) significantly enhances its selectivity for CO2 capture from flue gases and air. The structure and CO2 capacity of such materials are typically assessed using bulk techniques that
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