HAL (France)
open access
Boron difluorides with formazanate ligands: redox-switchable fluorescent dyes with large stokes shifts
The synthesis of a series of (formazanate)boron difluorides and their 1-electron reduction products is described. The neutral compounds are fluorescent with large Stokes shifts. DFT calculations suggest that a large structural reorganization accompanies photoexictation and accounts for the large Sto
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