HAL (France)
open access
Stepwise and reversible assembly of [2Fe-2S] rhombs to [8Fe-8S] clusters and their topological interconversions
Among all enzymatic metallocofactors, those found in nitrogenases, the P and L or M clusters, stand out for their intricate structures. They are assembled by proteins of the Nif gene cluster from Fe2S2 rhombs-the smallest building blocks in FeS cluster chemistry-through a sequence of reactions const
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