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Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides

Maity, Niladri et al.
eScholarship · Papers · License: CC BY
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The well-defined single-site silica-supported tungsten complex [([triple bond, length as m-dash]Si-O-)W(Me)5], 1, is an excellent precatalyst for alkane metathesis. The unique structure of 1 allows the synthesis of unprecedented tungsten hydrido methyl surface complexes via a controlled hydrogenolys
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