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Effect of Size Asymmetry and Zwitterionic Character of Solvent Ions on Impedance Spectra of Ultradilute Colloidal Suspensions
Buffer chemistry modulates colloidal impedance critically for label-free biosensing and electrokinetic diagnostics, yet classical models neglect buffer-specific interactions. We studied carboxylated polystyrene (PS) microspheres in conductivity-matched zwitterionic 4-(2-hydroxyethyl)-1-piperazineeth
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