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Near-Infrared Emitting Cu(I) Cluster-Based Metal–Organic Frameworks with Thermally Activated Delayed Fluorescence
Reaction of 4-methylpyrimidine-2-thione (Hmpymt) with excess CuCl or CuCN at 150 °C gave two [Cu6(mpymt)6] cluster-based metal–organic frameworks {(CuCl)4[Cu6(mpymt)6]}n (1) and {(CuCN)4[Cu6(mpymt)<
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