ABSTRACT
Abstract
The system includes an exhaust fuel gas line, an exhaust-fuel-gas supplying line, a recirculating line that circulates the exhaust fuel gas to the SOFC, a shut-off valve in a vent line that splits off on the upstream side of the branching point, an orifice on the downstream side of the shut-off valve, a water supplying portion that supplies water to the recirculating line, and a DPX that measures the system pressure difference of the SOFC, and, when stopping power generation by the SOFC or when power generation by the SOFC comes to an abnormal stop, the shut-off valve is opened, while causing a predetermined amount of pressure loss in the vent line by using the orifice, and thus, the water flow volume of the water supplying portion is controlled so that the pressure difference measured by the DPX reaches a predetermined value.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is based on Japanese Patent Application No. 2014-221582, the contents of which are incorporated herein by reference.
TECHNICAL FIELD
The present invention relates to a combined power generation system and to a unit, a method, and a program for controlling the same.
BACKGROUND ART
Fuel cells are power generation devices that utilize a power generation system based on electrochemical reactions, and have characteristics such as excellent power generation efficiency, environmental compatibility, and so forth. Such fuel cells are formed of a fuel electrode, which is a fuel-side electrode, an air electrode, which is an air (oxidant)-side electrode, and an electrolyte that is disposed between them and that allows only ions to pass therethrough, and various systems have been developed in accordance with types of electrolytes.
Among these, solid oxide fuel cells (hereinafter, referred to as âSOFCâ) are fuel cells that employ ceramics, such as zirconia ceramics or the like, as an electrolyte and that are operated by using, as fuel, hydrogen and hydrocarbon-based gas, such as carbon monoxide, methane or the like, gas generated by means of equipment that gasifies carbonaceous raw materials such as coal or the like, city gas, natural gas, or mixed gas containing a plurality of these components. Such an SOFC enables power generation with high power generation efficiency, for example, by constructing a combined power generation system in combination with an internal combustion engine, such as a micro gas turbine (hereinafter, referred to as âMGTâ) or the like.
In SOFCs, a technology has been under consideration in which, when power generation is stopped or tripped, a fuel-gas supplying system, an oxidizing-gas supplying system, a fuel-gas exhausting system, and an oxidizing-gas exhausting system are shut off, thus creating a state in which fuel gas and compressed oxidizing gas are contained in the SOFC system, and the SOFC is protected at this time by controlling the system pressure difference between the fuel system and the air system associated with stopping power generation by purging inert gas, such as nitrogen, onto the fuel electrode.
Patent Literature 1 described below discloses a technology used in a combined power generation system in which an SOFC and gas-turbine power generation equipment are combined for supplying pressure adjusting gas, such as reducing gas, nitrogen gas, or the like, in order to prevent a pressure drop associated with a temperature drop in the system in the case in which power generation is stopped, a fuel supplying system and an oxidizing-gas supplying system are shut off, and aeration gas is contained inside the SOFC system.
Patent Literature 2 described below discloses a technology used in a power generation system, having a vaporizer that vaporizes mixed liquid of fuel and water when the operation of power generating cells is stopped and a reformer that generates reformed gas containing hydrogen gas and carbon monoxide gas from the mixed gas, for adjusting internal pressures of individual channels, namely, an air channel, a fuel channel, an off-gas channel, and a water channel, by setting the vaporizer temperature at a higher temperature than the boiling point of the water and by making the water pass through the vaporizer to form water vapor.
Patent Literature 3 described below discloses a technology that maintains the internal pressures of fuel cells at atmospheric pressure by replenishing fuel gas, reducing gas, or inert gas.
CITATION LIST
Patent Literature
{PTL 1} Japanese Unexamined Patent Application, Publication No. 2014-89823
{PTL 2} Publication of Japanese Patent No. 4772470
{PTL 3} Publication of Japanese Patent No. 5446184
SUMMARY OF INVENTION
Technical Problem
However, to control the pressure difference by using nitrogen when power generation is stopped, because the amount of nitrogen used is increased, there has been a problem in that introduction of the SOFC system is limited to a site where satisfactory nitrogen utility equipment can be prepared, which is a factor that impedes the marketability thereof. In addition, there is a problem in that, because running costs associated with nitrogen consumption are increased, nitrogen consumption is suppressed as much as possible, even at sites equipped with equipment for utilizing nitrogen, and thus, the economic efficiency is decreased.
In addition, as in Patent Literature 2 described above, in the case in which water vapor is used, it is necessary to provide a vaporizer, and thus, it is not possible to solve the economic efficiency problems.
The present invention has been conceived in order to solve the above-described problems, and an object thereof is to provide a combined power generation system with which equipment costs and running costs can be suppressed and to provide a unit, a method, and a program for controlling the same.
Solution to Problem
A first aspect of the present invention is a control unit of a combined power generation system that combines a fuel cell and an internal combustion engine, the combined power generation system including an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower; an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine; a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell; a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point; a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line; a water supplying means for supplying liquid-phase water to the recirculating line; and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell, wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control unit opens the shut-off valve, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus controls a water flow volume of the water supplying means so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
With the first aspect of the present invention, in the combined power generation system that combines the fuel cell and the internal combustion engine and that is equipped with the exhaust fuel gas line that feeds the exhaust fuel gas from the fuel cell by means of the blower, the exhaust-fuel-gas supplying line that splits off from the branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, and the recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, when stopping power generation by the fuel cell or when power generation by the fuel cell comes to an abnormal stop, the pressure loss means on the downstream side of the shut-off valve provided in the vent line that splits off from the upstream side of the branching point causes the predetermined amount of pressure loss in the vent line, the shut-off valve of the vent line is opened, and thus, the water flow volume of the liquid-phase water supplied to the recirculating line is controlled so that the pressure difference between the air system and the fuel system of the fuel cell reaches the predetermined value.
The water supplied from the recirculating line is vaporized by the high-temperature exhaust fuel gas (for example, 250 to 500° C.) circulating in the recirculating line to form vapor and is supplied to the fuel-cell side. The fuel side is maintained at a positive pressure in this way, and the system pressure difference between the air system and the fuel system of the fuel cell is controlled by using water.
With this configuration, because water, which is lower cost than nitrogen, is used to control the system pressure difference between the air system and the fuel system of the fuel cell, the running cost thereof is suppressed, and thus, a high economic efficiency is achieved. In addition, storage of water is also easy. In addition, cost reduction is achieved by preventing nitrogen from being supplied from a recirculating line.
Although an amount of water (H 2 O) equal to or greater than a certain amount is required to prevent carbon deposition in the fuel electrode (anode), because water is supplied in the first aspect of the present invention, a sufficient amount of water can also be ensured from the viewpoint of carbon deposition prevention.
In the control unit of the combined power generation system according to the first aspect of the present invention, the pressure of the fuel system may be adjusted by opening/closing the shut-off valve or by controlling the water flow volume of the water supplying means.
With the above-described aspect, although back pressure cannot be adjusted during an interlock or trip operation in the case in which the internal combustion engine has failed or the like, it is possible to adjust the pressure on the water supply side by shutting the shut-off valve of the vent line. Because the pressure can be adjusted on the water supply side by shutting the shut-off valve of the vent line, it is possible to quickly respond to an increase in the pressure on the fuel side by intermittently operating the shut-off valve. In addition, a shut-off valve is lower cost than a control valve, and the cost thereof is relatively low.
In the control unit of the combined power generation system according to the first aspect of the present invention, it is preferable that the water supplying means be equipped with a spraying means for supplying the water by means of spraying.
With the above-described aspect, by supplying water to the recirculating line by spraying the water, vaporization thereof is facilitated, and the pressure difference can be controlled in a simple manner by using water.
In the control unit of the combined power generation system according to the first aspect of the present invention, the pressure of the fuel system may be adjusted by controlling the water flow volume from the water supplying means and also by controlling a nitrogen-supply flow volume to the recirculating line.
With the above-described aspect, it is possible to control the system pressure difference in a short period of time by using both water and nitrogen to be supplied to the recirculating line.
With the control unit of the combined power generation system according to the first aspect of the present invention, in a case in which power generation by the fuel cell comes to an abnormal stop and containment is required, the pressure of the fuel system may be adjusted by supplying water from the water supplying means, when the pressure of the fuel system becomes lower than a pressure of the air system by an amount equal to or greater than a predetermined pressure.
With the above-described aspect, in the case in which the fuel system pressure becomes lower than the air system pressure by an amount equal to or greater than the predetermined pressure when containment is required, and thus, the system pressure difference is increased, it is possible to adjust the fuel system pressure in a simple manner by supplying the water.
With the control unit of the combined power generation system according to the first aspect of the present invention, in a case in which power generation by the fuel cell comes to an abnormal stop and containment is required, the pressure of the fuel system may be adjusted by opening the shut-off valve, when the pressure of the fuel system becomes greater than the pressure of the air system by an amount equal to or greater than a predetermined pressure.
With the above-described aspect, in the case in which the fuel system pressure becomes greater than the air system pressure by an amount equal to or greater than the predetermined pressure when containment is required, and thus, the system pressure difference is increased, it is possible to adjust the fuel system pressure in a simple manner by opening the shut-off valve.
A second aspect of the present invention provides a combined power generation system provided with any one of the above-described control units.
A third aspect of the present invention is a control method of a combined power generation system that combines a fuel cell and an internal combustion engine and that is equipped with an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower, an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point, a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line, a water supplying means for supplying liquid-phase water to the recirculating line, and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell, wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control method opens the shut-off valve, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus controls a water flow volume of the water supplying means so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
A fourth aspect of the present invention is a control program of a combined power generation system that combines a fuel cell and an internal combustion engine and that is equipped with an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower, an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point, a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line, a water supplying means for supplying liquid-phase water to the recirculating line, and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell, wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control program causes a computer to execute control in which the shut-off valve is opened, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus, a water flow volume of the water supplying means is controlled so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
Advantageous Effects of Invention
The present invention affords an advantage in that it is possible to control combined power generation equipment while suppressing equipment costs and running costs thereof.
BRIEF DESCRIPTION OF DRAWINGS
FIG. 1 is a schema
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is based on Japanese Patent Application No. 2014-221582, the contents of which are incorporated herein by reference.
TECHNICAL FIELD
The present invention relates to a combined power generation system and to a unit, a method, and a program for controlling the same.
BACKGROUND ART
Fuel cells are power generation devices that utilize a power generation system based on electrochemical reactions, and have characteristics such as excellent power generation efficiency, environmental compatibility, and so forth. Such fuel cells are formed of a fuel electrode, which is a fuel-side electrode, an air electrode, which is an air (oxidant)-side electrode, and an electrolyte that is disposed between them and that allows only ions to pass therethrough, and various systems have been developed in accordance with types of electrolytes.
Among these, solid oxide fuel cells (hereinafter, referred to as âSOFCâ) are fuel cells that employ ceramics, such as zirconia ceramics or the like, as an electrolyte and that are operated by using, as fuel, hydrogen and hydrocarbon-based gas, such as carbon monoxide, methane or the like, gas generated by means of equipment that gasifies carbonaceous raw materials such as coal or the like, city gas, natural gas, or mixed gas containing a plurality of these components. Such an SOFC enables power generation with high power generation efficiency, for example, by constructing a combined power generation system in combination with an internal combustion engine, such as a micro gas turbine (hereinafter, referred to as âMGTâ) or the like.
In SOFCs, a technology has been under consideration in which, when power generation is stopped or tripped, a fuel-gas supplying system, an oxidizing-gas supplying system, a fuel-gas exhausting system, and an oxidizing-gas exhausting system are shut off, thus creating a state in which fuel gas and compressed oxidizing gas are contained in the SOFC system, and the SOFC is protected at this time by controlling the system pressure difference between the fuel system and the air system associated with stopping power generation by purging inert gas, such as nitrogen, onto the fuel electrode.
Patent Literature 1 described below discloses a technology used in a combined power generation system in which an SOFC and gas-turbine power generation equipment are combined for supplying pressure adjusting gas, such as reducing gas, nitrogen gas, or the like, in order to prevent a pressure drop associated with a temperature drop in the system in the case in which power generation is stopped, a fuel supplying system and an oxidizing-gas supplying system are shut off, and aeration gas is contained inside the SOFC system.
Patent Literature 2 described below discloses a technology used in a power generation system, having a vaporizer that vaporizes mixed liquid of fuel and water when the operation of power generating cells is stopped and a reformer that generates reformed gas containing hydrogen gas and carbon monoxide gas from the mixed gas, for adjusting internal pressures of individual channels, namely, an air channel, a fuel channel, an off-gas channel, and a water channel, by setting the vaporizer temperature at a higher temperature than the boiling point of the water and by making the water pass through the vaporizer to form water vapor.
Patent Literature 3 described below discloses a technology that maintains the internal pressures of fuel cells at atmospheric pressure by replenishing fuel gas, reducing gas, or inert gas.
CITATION LIST
Patent Literature
{PTL 1} Japanese Unexamined Patent Application, Publication No. 2014-89823
{PTL 2} Publication of Japanese Patent No. 4772470
{PTL 3} Publication of Japanese Patent No. 5446184
SUMMARY OF INVENTION
Technical Problem
However, to control the pressure difference by using nitrogen when power generation is stopped, because the amount of nitrogen used is increased, there has been a problem in that introduction of the SOFC system is limited to a site where satisfactory nitrogen utility equipment can be prepared, which is a factor that impedes the marketability thereof. In addition, there is a problem in that, because running costs associated with nitrogen consumption are increased, nitrogen consumption is suppressed as much as possible, even at sites equipped with equipment for utilizing nitrogen, and thus, the economic efficiency is decreased.
In addition, as in Patent Literature 2 described above, in the case in which water vapor is used, it is necessary to provide a vaporizer, and thus, it is not possible to solve the economic efficiency problems.
The present invention has been conceived in order to solve the above-described problems, and an object thereof is to provide a combined power generation system with which equipment costs and running costs can be suppressed and to provide a unit, a method, and a program for controlling the same.
Solution to Problem
A first aspect of the present invention is a control unit of a combined power generation system that combines a fuel cell and an internal combustion engine, the combined power generation system including an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower; an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine; a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell; a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point; a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line; a water supplying means for supplying liquid-phase water to the recirculating line; and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell, wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control unit opens the shut-off valve, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus controls a water flow volume of the water supplying means so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
With the first aspect of the present invention, in the combined power generation system that combines the fuel cell and the internal combustion engine and that is equipped with the exhaust fuel gas line that feeds the exhaust fuel gas from the fuel cell by means of the blower, the exhaust-fuel-gas supplying line that splits off from the branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, and the recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, when stopping power generation by the fuel cell or when power generation by the fuel cell comes to an abnormal stop, the pressure loss means on the downstream side of the shut-off valve provided in the vent line that splits off from the upstream side of the branching point causes the predetermined amount of pressure loss in the vent line, the shut-off valve of the vent line is opened, and thus, the water flow volume of the liquid-phase water supplied to the recirculating line is controlled so that the pressure difference between the air system and the fuel system of the fuel cell reaches the predetermined value.
The water supplied from the recirculating line is vaporized by the high-temperature exhaust fuel gas (for example, 250 to 500° C.) circulating in the recirculating line to form vapor and is supplied to the fuel-cell side. The fuel side is maintained at a positive pressure in this way, and the system pressure difference between the air system and the fuel system of the fuel cell is controlled by using water.
With this configuration, because water, which is lower cost than nitrogen, is used to control the system pressure difference between the air system and the fuel system of the fuel cell, the running cost thereof is suppressed, and thus, a high economic efficiency is achieved. In addition, storage of water is also easy. In addition, cost reduction is achieved by preventing nitrogen from being supplied from a recirculating line.
Although an amount of water (H 2 O) equal to or greater than a certain amount is required to prevent carbon deposition in the fuel electrode (anode), because water is supplied in the first aspect of the present invention, a sufficient amount of water can also be ensured from the viewpoint of carbon deposition prevention.
In the control unit of the combined power generation system according to the first aspect of the present invention, the pressure of the fuel system may be adjusted by opening/closing the shut-off valve or by controlling the water flow volume of the water supplying means.
With the above-described aspect, although back pressure cannot be adjusted during an interlock or trip operation in the case in which the internal combustion engine has failed or the like, it is possible to adjust the pressure on the water supply side by shutting the shut-off valve of the vent line. Because the pressure can be adjusted on the water supply side by shutting the shut-off valve of the vent line, it is possible to quickly respond to an increase in the pressure on the fuel side by intermittently operating the shut-off valve. In addition, a shut-off valve is lower cost than a control valve, and the cost thereof is relatively low.
In the control unit of the combined power generation system according to the first aspect of the present invention, it is preferable that the water supplying means be equipped with a spraying means for supplying the water by means of spraying.
With the above-described aspect, by supplying water to the recirculating line by spraying the water, vaporization thereof is facilitated, and the pressure difference can be controlled in a simple manner by using water.
In the control unit of the combined power generation system according to the first aspect of the present invention, the pressure of the fuel system may be adjusted by controlling the water flow volume from the water supplying means and also by controlling a nitrogen-supply flow volume to the recirculating line.
With the above-described aspect, it is possible to control the system pressure difference in a short period of time by using both water and nitrogen to be supplied to the recirculating line.
With the control unit of the combined power generation system according to the first aspect of the present invention, in a case in which power generation by the fuel cell comes to an abnormal stop and containment is required, the pressure of the fuel system may be adjusted by supplying water from the water supplying means, when the pressure of the fuel system becomes lower than a pressure of the air system by an amount equal to or greater than a predetermined pressure.
With the above-described aspect, in the case in which the fuel system pressure becomes lower than the air system pressure by an amount equal to or greater than the predetermined pressure when containment is required, and thus, the system pressure difference is increased, it is possible to adjust the fuel system pressure in a simple manner by supplying the water.
With the control unit of the combined power generation system according to the first aspect of the present invention, in a case in which power generation by the fuel cell comes to an abnormal stop and containment is required, the pressure of the fuel system may be adjusted by opening the shut-off valve, when the pressure of the fuel system becomes greater than the pressure of the air system by an amount equal to or greater than a predetermined pressure.
With the above-described aspect, in the case in which the fuel system pressure becomes greater than the air system pressure by an amount equal to or greater than the predetermined pressure when containment is required, and thus, the system pressure difference is increased, it is possible to adjust the fuel system pressure in a simple manner by opening the shut-off valve.
A second aspect of the present invention provides a combined power generation system provided with any one of the above-described control units.
A third aspect of the present invention is a control method of a combined power generation system that combines a fuel cell and an internal combustion engine and that is equipped with an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower, an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point, a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line, a water supplying means for supplying liquid-phase water to the recirculating line, and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell, wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control method opens the shut-off valve, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus controls a water flow volume of the water supplying means so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
A fourth aspect of the present invention is a control program of a combined power generation system that combines a fuel cell and an internal combustion engine and that is equipped with an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower, an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point, a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line, a water supplying means for supplying liquid-phase water to the recirculating line, and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell, wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control program causes a computer to execute control in which the shut-off valve is opened, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus, a water flow volume of the water supplying means is controlled so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
Advantageous Effects of Invention
The present invention affords an advantage in that it is possible to control combined power generation equipment while suppressing equipment costs and running costs thereof.
BRIEF DESCRIPTION OF DRAWINGS
FIG. 1 is a schematic configuration diagram of a combined power generation system according to the present invention.
FIG. 2 is a sectional view of an example cell stack for an SOFC that constitutes the combined power generation system shown in FIG. 1 .
FIG. 3 is a system diagram in which a cartridge and the peripheries thereof are enlarged, in the SOFC that constitutes the combined power generation system shown in FIG. 1 .
FIG. 4 shows an operation flow of a control unit of the combined power generation system according to the present invention.
FIG. 5 shows a continuation of the operation flow of the control unit of the combined power generation system shown in FIG. 4 .
DESCRIPTION OF EMBODIMENT
An embodiment of a combined power generation system according to the present invention and a unit, a method, and a program for controlling the same will be described below with reference to the drawings.
A combined power generation system 1 shown in FIG. 1 is provided with an SOFC 10 , which is a high-temperature type fuel cell, a micro gas turbine (hereinafter, referred to as âMGTâ) 50 , which is an example of gas turbines and gas engines, that is to say, internal combustion engines, and a control unit 90 , and performs efficient power generation by combining the SOFC 10 and the MGT 50 .
Specifically, in addition to the SOFC 10 that generates power by means of electrochemical reactions via an electrolyte by receiving supplies of fuel gas, which is reformed from city gas (natural gas) or the like, and oxidizing gas such as air or the like, the MGT 50 is operated by using combustion gas by introducing high-temperature exhaust fuel and exhaust air expelled from the SOFC 10 after generating power into a combustor, and power is generated by driving a generator (not shown) coupled with an output shaft of the MGT 50 . Note that, oxidizing gas is gas containing substantially 15 to 30% oxygen, and, although air is typically preferable, aside from air, a mixed gas containing combustion exhaust gas and air, a mixed gas containing oxygen and air, or the like can be used.
Furthermore, by introducing the high-temperature combustion exhaust gas to the exhaust-heat recovery boiler expelled from the MGT 50 , it is also possible to construct a combined power generation system combined with power generation based on a steam turbine that is driven by the generated vapor.
In the following, the combined power generation system 1 employing the above-described SOFC 10 will be described. This SOFC 10 employs ceramics, such as zirconia ceramics, as an electrolyte, and is operated (generates power) by using city gas, natural gas, oil, methanol, coal gasification gas, or the like as fuel, and the operating temperature thereof is set high, at about 800 to 1000° C., in order to increase the ionic conductivity.
In the following, for the convenience of explaining, although positional relationships of individual components will be specified by using expressions âtopâ and âbottomâ with reference to the plane of the figures, this need not necessarily correspond to top and bottom in the vertical direction. For example, the top direction in the plane of a figure may correspond to the bottom direction in the vertical direction. In addition, the top-to-bottom direction in the plane of a figure may correspond to the horizontal direction that is perpendicular to the vertical direction.
In addition, in the following, although a cell stack of the solid oxide fuel cell (SOFC) will be described by using a cylindrical shape as an example, the shape thereof need not necessarily be limited thereto, and, for example, the cell stack may have a flat plate shape.
A cylindrical cell stack according to this Example will be described with reference to FIG. 2 . Here, FIG. 2 shows a form of the cell stack according to this embodiment. A cell stack 101 has a cylindrical substrate tube 103 , a plurality of fuel-cell cells 105 formed on an outer circumferential surface of the substrate tube 103 , and interconnectors 107 formed between adjacent fuel-cell cells 105 . The fuel-cell cells 105 are formed by stacking fuel electrodes (anode) 109 , solid electrolytes 111 , and air electrodes (cathode) 113 . In addition, among the plurality of fuel-cell cells 105 formed on the outer circumferential surface of the substrate tube 103 , the cell stack 101 has a lead film 115 that is electrically connected to the air electrode (cathode) 113 of the fuel-cell cell 105 formed at the furthest end of the substrate tube 103 in the axial direction via the interconnector 107 thereof.
The substrate tube 103 is formed of a porous material, namely, for example, CaO stabilized ZrO 2 (CSZ: calcia stabilized zirconia), Y 2 O 3 stabilized ZrO 2 (YSZ: yttria stabilized zirconia), or MgAl 2 O 4 . The substrate tube 103 supports the fuel-cell cells 105 , the interconnectors 107 , and the lead film 115 , and also allows the fuel gas that is supplied to an inner circumferential surface of the substrate tube 103 to diffuse toward the fuel electrodes (anode) 109 formed at an outer circumferential surface of the substrate tube 103 via micropores of the substrate tube 103 .
The fuel electrodes (anode) 109 are formed of an oxide of a composite material of Ni and a zirconia-based electrolyte material, and, for example, Ni/YSZ is used. With the fuel electrodes (anode) 109 in this case, Ni, which is the component of the fuel electrodes (anode) 109 , has a catalytic effect on the fuel gas. This catalytic effect causes the fuel gas supplied via the substrate tube 103 , for example, a mixed gas containing methane (CH 4 ) and water vapor, to react, thus reforming the mixed gas into hydrogen (H 2 ) and carbon monoxide (CO). In addition, the fuel electrodes (anode) 109 cause hydrogen (H 2 ) and carbon monoxide (CO) obtained by the reformation to electrochemically react with oxygen ions (O 2â ) supplied via the solid electrolytes 111 in the vicinity of the interfaces with the solid electrolytes 111 , thus generating water (H 2 O) and carbon dioxide (CO 2 ). Note that, at this time, the fuel-cell cells 105 generate power by means of electrons released from the oxygen ions.
YSZ, which has airtightness with low gas permeability and high oxygen-ion conductivity at high temperature, is mainly used for the solid electrolytes 111 . The solid electrolytes 111 allow the oxygen ions (O 2â ) generated at the air electrodes (cathode) 113 to move toward the fuel electrodes (anode) 109 .
The air electrodes (cathode) 113 are formed of, for example, a LaSrMnO 3 -based oxide or a LaCoO 3 -based oxide. In the vicinity of the interfaces with the solid electrolytes 111 , the air electrodes (cathode) 113 generate the oxygen ions (O 2â ) by dissociating oxygen in oxidizing gas, such as the supplied air or the like.
The interconnectors 107 are formed of a conductive perovskite oxide denoted as M 1-x L x TiO 3 (M is an alkaline earth metal element and L is a lanthanoid element), such as a SrTiO 3 -based oxide, and form a dense film so as to prevent mixing of the fuel gas and the oxidizing gas. In addition, the interconnectors 107 have stable electrical conductivity both in an oxidizing atmosphere and a reducing atmosphere. The interconnectors 107 electrically connect the air electrode (cathode) 113 of one of the fuel-cell cells 105 and the fuel electrode (anode) 109 of the other fuel-cell cell 105 in the adjacent fuel-cell cells 105 , thus connecting the adjacent fuel-cell cells 105 with each other in series. The lead film 115 is formed of a composite material of Ni and a zirconia-based electrolyte material, such as Ni/YSZ or the like, because the lead film 115 needs to have electron conductivity and a thermal expansion coefficient that is close to those of other materials forming the cell stack 101 . The lead film 115 leads out the DC electric power generated by the plurality of fuel-cell cells 105 connected in series by the interconnectors 107 to the vicinity of the end portion of the cell stack 101 .
The fuel electrodes (anode) 109 receive a supply of fuel, such as natural gas or the like, from a fuel supplying system 20 , and expel the fuel gas supplied to the SOFC 10 to a fuel-gas exhausting system 27 .
The air electrodes (cathode) 113 receive a supply of air from an oxidizing- gas supplying system 70 , and expel high-temperature exhaust air that has been utilized in electrochemical reactions to an oxidizing-gas exhausting system 72 . The oxidizing- gas supplying system 70 is connected to a compressor 51 of a turbine 53 , to be described below, and the oxidizing-gas exhausting system 72 is connected to a combustor 52 of the turbine 53 .
Note that an SOFC module has a plurality of SOFC cartridges 11 (see FIG. 3 ) and a pressure vessel 81 that accommodates the plurality of SOFC cartridges.
As shown in FIG. 3 , each SOFC cartridge 11 includes a plurality of cell stacks 101 , a power generation chamber 13 , a fuel- gas supplying chamber 14 , a fuel- gas exhausting chamber 15 , an oxidizing- gas supplying chamber 16 , and an oxidizing- gas exhausting chamber 17 .
The SOFC cartridges 11 of this embodiment have tube plates
82 a and 82 b that partition the space in the longitudinal direction of the cell stacks 101 to form the fuel- gas supplying chamber 14 and the fuel- gas exhausting chamber 15 , a heat insulation plate 83 b that partitions the space in the longitudinal direction of the cell stacks 101 to form the oxidizing- gas supplying chamber 16 between the tube plate 82 b and the heat insulation plate 83 b , and a heat insulation plate 83 a that forms the oxidizing- gas exhausting chamber 17 between the tube plate 82 a and the heat insulation plate 83 a , and, as shown in FIG. 3 , the fuel- gas supplying chamber 14 , the oxidizing- gas exhausting chamber 17 , the power generation chamber 13 , the oxidizing- gas supplying chamber 16 , and the fuel- gas exhausting chamber 15 are formed and disposed in this order from top to bottom in the plane of the figure.
By arranging the fuel- gas supplying chamber 14 , the fuel- gas exhausting chamber 15 , the oxidizing- gas supplying chamber 16 , and the oxidizing- gas exhausting chamber 17 , a structure in which the fuel gas and the oxidizing gas flow in opposite directions inside and outside the cell stacks 101 is formed. However, it is not necessarily limited to this arrangement and structure, and, for example, the flows inside and outside the cell stacks may be parallel to each other or the oxidizing gas may be made to flow in a direction perpendicular to the longitudinal direction of the cell stacks.
The power generation chamber 13 is a region formed between the oxidizing- gas supplying chamber 16 and the oxidizing- gas exhausting chamber 17 . This power generation chamber 13 is a region in which the fuel-cell cells of the cell stacks 101 are disposed, and in which power is generated by making the fuel gas and the oxidizing gas electrochemically react with each other. In addition, the temperature near the center portion of the power generation chamber 13 in the longitudinal direction of the cell stacks 101 reaches high-temperature atmosphere of about 800 to 1000° C. during steady state operation of the fuel-cell module.
In the fuel- gas supplying chamber 14 , first end portions of the cell stacks 101 are disposed so that the interiors of the substrate tubes 103 of the cell stacks 101 are open toward the fuel- gas supplying chamber 14 . This fuel- gas supplying chamber 14 guides the fuel gas, which is supplied thereto from a fuel-gas supplying pipe branch (not shown) via a fuel-gas supplying hole, to the interiors of the substrate tubes 103 of the plurality of cell stacks 101 at a substantially uniform flow volume to make the power generation performance of the plurality of cell stacks 101 substantially uniform.
In the fuel- gas exhausting chamber 15 , second end portions of the cell stacks 101 are disposed so that the interiors of the substrate tubes 103 of the cell stacks 101 are open toward the fuel- gas exhausting chamber 15 . This fuel- gas exhausting chamber 15 collects the exhaust fuel gas that passes through the interiors of the substrate tubes 103 of the plurality of cell stacks 101 and that is supplied to the fuel- gas exhausting chamber 15 and guides the exhaust fuel gas to a fuel-gas exhausting pipe branch via a fuel-gas exhausting hole (not shown).
In this embodiment, due to the structure of the SOFC cartridges 11 described above, the fuel gas and the oxidizing gas flow in opposite directions inside and outside of the cell stacks 101 . Because of this, the exhaust oxidizing gas undergoes heat exchange with the fuel gas that passes through the interiors of the substrate tubes 103 and that is supplied to the power generation chamber 13 , is cooled to a temperature at which a deformation such as buckling or the like does not occur in a top-portion tube plate or the like that is formed of a metal material, and is supplied to the oxidizing- gas exhausting chamber 15 . In addition, the fuel gas is heated by heat exchange with the exhaust oxidizing gas expelled from the power generation chamber 13 and is supplied to the power generation chamber 13 . As a result, it is possible to supply the power generation chamber 13 with the fuel gas which has been preheated to an appropriate temperature for power generation without employing a heater or the like.
In the following description, although a case in which city gas is used as fuel by reforming it outside or inside the SOFC 10 and air is used as oxidizing gas will be described, the air in this case is compressed air that is supplied from the MGT 50 . Alternatively, the air may be supplied by separately providing an air compressor.
As shown in FIG. 1 , the MGT 50 is provided with, for example, the compressor 51 , the combustor 52 , and the turbine 53 . Note that, in the figure, reference sign 54 indicates a filter and 55 indicates a regenerative heat exchanger. The compressor 51 compresses the atmosphere (air) introduced via the filter 54 , and, in this case, the turbine 53 serves as the driving source thereof. The compressed air that has been compressed at the compressor 51 is supplied to the SOFC 10 or the like via the combustor 52 and the regenerative heat exchanger 55 . The combustor 52 combusts city gas, which is the fuel, by receiving the supplied compressed air, generates high-temperature, high-pressure combustion exhaust gas, and supplies it to the turbine 53 . An exhaust-fuel- gas supplying line 27 c , to be described below, and a fuel- gas supplying system 40 that supplies unused city gas (fuel gas) are connected to this combustor 52 .
The turbine 53 is rotated by the energy of the combustion exhaust gas and generates shaft output, and the compressor 51 and a generator (not shown) are driven by utilizing this shaft output. The combustion exhaust gas that has performed work at the turbine 53 is released into the atmosphere from a stack 60 after heating the compressed air at the regenerative heat exchanger 55 by means of heat exchange therewith.
The combined power generation system 1 is a system that generates power by combining the SOFC 10 and the MGT 50 , and is provided with the fuel supplying system 20 that supplies fuel to the fuel electrodes (anode) 109 and the oxidizing- gas supplying system 70 that supplies oxidizing gas to the air electrodes (cathode) 113 .
The fuel supplying system 20 is provided with a water supplying line 22 a provided with a feed pump 23 , a nitrogen supplying line 22 b provided with a nitrogen-supplying valve (open/close valve) 21 b , and a city-gas (fuel-gas) supplying line 22 c provided with a city-gas supplying valve (open/close valve) 21 c.
The water supplying line 22 a is provided with a water supplying portion (water supplying means) 24 at a portion joining with a recirculating line 27 b (to be described below). This embodiment will be described assuming that the water supplying portion 24 is a spray (spraying means) that supplies water by means of spraying. By spraying water from the water supplying portion 24 , water is supplied to the recirculating line 27 b . When water is sprayed from the water supplying portion 24 , water is vaporized because the exhaust fuel gas circulating in the recirculating line 27 b is at a high temperature (for example, 250 to 500° C.), and thus, vapor is supplied to the SOFC 10 .
The fuel-gas exhausting system 27 is a channel that feeds the fuel gas supplied to the SOFC 10 to the MGT 50 . This fuel-gas <figure-callout id="27" label="exhausting system" filenames="US09666
CLAIMS
Claims ( 9 )
The invention claimed is:
1. A control unit of a combined power generation system that combines a fuel cell and an internal combustion engine,
the combined power generation system comprising:
an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower;
an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine;
a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell;
a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point;
a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line;
a water supplying means for supplying liquid-phase water to the recirculating line; and
a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell,
wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop,
the control unit opens the shut-off valve, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus controls a water flow volume of the water supplying means so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
2. A control unit of a combined power generation system according to claim 1 , wherein a pressure of the fuel system is adjusted by opening/closing the shut-off valve or by controlling the water flow volume of the water supplying means.
3. A control unit of a combined power generation system according to claim 1 , wherein the water supplying means is equipped with a spraying means for supplying the water by means of spraying.
4. A control unit of a combined power generation system according to any one of claim 1 , wherein the pressure of the fuel system is adjusted by controlling the water flow volume from the water supplying means and also by controlling a nitrogen-supply flow volume to the recirculating line.
5. A control unit of a combined power generation system according to any one of claim 1 , wherein, in a case in which power generation by the fuel cell comes to an abnormal stop and containment is required,
the pressure of the fuel system is adjusted by supplying water from the water supplying means, when the pressure of the fuel system becomes lower than a pressure of the air system by an amount equal to or greater than a predetermined pressure.
6. A control unit of a combined power generation system according to any one of claim 1 , wherein, in a case in which power generation by the fuel cell comes to an abnormal stop and containment is required,
the pressure of the fuel system is adjusted by opening the shut-off valve, when the pressure of the fuel system becomes greater than the pressure of the air system by an amount equal to or greater than a predetermined pressure.
7. A combined power generation system provided with a control unit according to any one of claim 1 .
8. A control method of a combined power generation system that combines a fuel cell and an internal combustion engine and that is equipped with an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower, an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point, a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line, a water supplying means for supplying liquid-phase water to the recirculating line, and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell,
wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control method opens the shut-off valve, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus controls a water flow volume of the water supplying means so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
9. A control program of a combined power generation system that combines a fuel cell and an internal combustion engine and that is equipped with an exhaust fuel gas line that feeds exhaust fuel gas from the fuel cell by means of a blower, an exhaust-fuel-gas supplying line that splits off from a branching point of the exhaust fuel gas line and that supplies the exhaust fuel gas to the internal combustion engine, a recirculating line that splits off from the branching point and that circulates the exhaust fuel gas to the fuel cell, a shut-off valve that is provided in a vent line that splits off on an upstream side of the branching point, a pressure loss means that is provided on a downstream side of the shut-off valve in the vent line, a water supplying means for supplying liquid-phase water to the recirculating line, and a system-pressure-difference measuring means for measuring a pressure difference between an air system and a fuel system of the fuel cell,
wherein, when stopping power generation by the fuel cell or when the power generation by the fuel cell comes to an abnormal stop, the control program causes a computer to execute control in which the shut-off valve is opened, while causing a predetermined amount of pressure loss in the vent line by using the pressure loss means, and thus, a water flow volume of the water supplying means is controlled so that the pressure difference measured by the system-pressure-difference measuring means reaches a predetermined value.
US14/923,926
2014-10-30
2015-10-27
Combined power generation system and unit, method, and program for controlling the same
Expired - Fee Related
US9666888B2
( en )
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
JP2014221582A
JP6472638B2
( en )
2014-10-30
2014-10-30
Combined power generation system, control device and method thereof, and program
JP2014-221582
2014-10-30
Publications (2)
Publication Number
Publication Date
US20160126570A1
US20160126570A1 ( en )
2016-05-05
US9666888B2
true
US9666888B2 ( en )
2017-05-30
Family
ID=55853655
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
US14/923,926
Expired - Fee Related
US9666888B2
( en )
2014-10-30
2015-10-27
Combined power generation system and unit, method, and program for controlling the same
Country Status (2)
Country
Link
US
( 1 )
US9666888B2
( en )
JP
( 1 )
JP6472638B2
( en )
Cited By (32)
* Cited by examiner, â Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US10724432B2
( en )
2017-11-07
2020-07-28
General Electric Company
Integrated fuel cell and engine combustor assembly
US11239470B2
( en )
2018-12-17
2022-02-01
General Electric Company
Integrated fuel cell and combustion system
US11719441B2
( en )
2022-01-04
2023-08-08
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US11794912B2
( en )
2022-01-04
2023-10-24
General Electric Company
Systems and methods for reducing emissions with a fuel cell
US11804607B2
( en )
2022-01-21
2023-10-31
General Electric Company
Cooling of a fuel cell assembly
US11817700B1
( en )
2022-07-20
2023-11-14
General Electric Company
Decentralized electrical power allocation system
US11859820B1
( en )
2022-11-10
2024-01-02
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US11923586B1
( en )
2022-11-10
2024-03-05
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US11933216B2
( en )
2022-01-04
2024-03-19
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US11967743B2
( en )
2022-02-21
2024-04-23
General Electric Company
Modular fuel cell assembly
US11970282B2
( en )
2022-01-05
2024-04-30
General Electric Company
Aircraft thrust management with a fuel cell
US12025061B2
( en )
2022-04-04
2024-07-02
General Electric Company
Gas turbine engine with fuel cell assembly
US12034298B2
( en )
2022-01-10
2024-07-09
General Electric Company
Power source for an aircraft
US12037124B2
( en )
2022-01-21
2024-07-16
General Electric Company
Systems and method of operating a fuel cell assembly
US12037952B2
( en )
2022-01-04
2024-07-16
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US12043406B2
( en )
2022-05-27
2024-07-23
General Electric Company
Method of operating a fuel cell assembly for an aircraft
US12074350B2
( en )
2022-01-21
2024-08-27
General Electric Company
Solid oxide fuel cell assembly
US12078350B2
( en )
2022-11-10
2024-09-03
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US12123361B2
( en )
2022-01-04
2024-10-22
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US12129789B2
( en )
2022-02-21
2024-10-29
General Electric Company
Systems and method of operating a fuel cell assembly, a gas turbine engine, or both
US12170390B2
( en )
2022-02-21
2024-12-17
General Electric Company
Systems and method of operating a fuel cell assembly, a gas turbine engine, or both
US12202616B2
( en )
2021-11-04
2025-01-21
General Electric Company
Relight of a propulsion system with a fuel cell
US12240613B2
( en )
2022-11-10
2025-03-04
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US12261334B2
( en )
2023-02-23
2025-03-25
General Electric Company
Gas turbine engine and fuel cell assembly
US12270340B2
( en )
2023-02-23
2025-04-08
General Electric Company
Gas turbine engine and fuel cell assembly
US12301002B2
( en )
2022-08-26
2025-05-13
General Electric Company
Power dispatch control system for multiple power generation sources
US12351329B2
( en )
2022-01-21
2025-07-08
General Electric Company
Systems and method of operating a fuel cell assembly
US12412914B2
( en )
2022-05-16
2025-09-09
General Electric Company
Environmental control system having a fuel cell assembly
US12428164B2
( en )
2022-05-16
2025-09-30
General Electric Company
Environmental control system having a fuel cell assembly
US12567595B2
( en )
2022-11-10
2026-03-03
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US12573647B2
( en )
2022-01-21
2026-03-10
General Electric Company
Solid oxide fuel cell assembly
US12584445B2
( en )
2023-02-23
2026-03-24
General Electric Company
Gas turbine engine and fuel cell assembly
Families Citing this family (16)
* Cited by examiner, â Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
WO2014080758A1
( en )
*
2012-11-21
2014-05-30
ä¸è±éå·¥æ¥æ ªå¼ä¼ç¤¾
Power generation system, method for powering power generation system, and combustor
JP6237861B1
( en )
*
2016-11-04
2017-11-29
å¯å£«é»æ©æ ªå¼ä¼ç¤¾
Fuel cell system and operation method thereof
KR102496639B1
( en )
*
2016-12-13
2023-02-07
íëìë차주ìíì¬
Fuel cell system and fuel cell stack housing
KR102119441B1
( en )
*
2018-02-15
2020-06-08
ë¯¸ì¸ ë¹ì ííì¹ íì ìì¤í ì¦ ê°ë¶ìí¤ê°ì´ì¤
Fuel cell system, combined power generation system, and control method for fuel cell system
AT521207B1
( en )
*
2018-05-03
2020-03-15
Avl List Gmbh
Fuel cell system and method for operating a fuel cell system
US10991963B2
( en )
*
2018-07-10
2021-04-27
Cummins Enterprise Llc
Fuel cell system and control method thereof
KR102714440B1
( en )
*
2018-10-23
2024-10-07
íëìë차주ìíì¬
Fuel cell system for continuously dischaging anode gas
US11196068B2
( en )
2019-01-29
2021-12-07
Bloom Energy Corporation
Fuel cell system containing water injector and method of operating the same
KR102603066B1
( en )
*
2019-03-20
2023-11-15
íëìë차주ìíì¬
Air conditioning system using fuel cell system
CN110828864B
( en )
*
2019-11-01
2021-02-19
ä¸è½¦å·¥ä¸ç 究é¢æéå ¬å¸
Non-auxiliary starting method and system for hydrogen-oxygen electrochemical reaction device
JP2021103642A
( en )
2019-12-25
2021-07-15
å¯å£«é»æ©æ ªå¼ä¼ç¤¾
Fuel cell system
JP6961736B2
( en )
*
2020-02-27
2021-11-05
ä¸è±ãã¯ã¼æ ªå¼ä¼ç¤¾
Fuel cell system and its control method
CN111933977A
( en )
*
2020-05-11
2020-11-13
åå°æ»¨å·¥ä¸å¤§å¦
Fuel cell-turbocharged internal combustion engine hybrid power generation system
JP7066797B2
( en )
*
2020-09-07
2022-05-13
ä¸è±éå·¥æ¥æ ªå¼ä¼ç¤¾
Fuel cell system and its control method, and power generation system and its control method
US12169069B2
( en )
*
2021-12-20
2024-12-17
General Electric Company
System for producing diluent for a gas turbine engine
SE547378C2
( en )
*
2022-10-27
2025-07-22
Volvo Truck Corp
Controlling pressure in a fuel cell system
Citations (5)
* Cited by examiner, â Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US6413662B1
( en )
*
2000-02-22
2002-07-02
General Motors Corporation
Fuel cell system shutdown with anode pressure control
US20070166598A1
( en )
2003-06-25
2007-07-19
Hydrogenics Corporation
Passive electrode blanketing in a fuel cell
JP4772470B2
( en )
2005-11-22
2011-09-14
ä¸è±é»æ©æ ªå¼ä¼ç¤¾
Fuel cell system
JP5446184B2
( en )
2008-09-12
2014-03-19
ã«ã·ãªè¨ç®æ©æ ªå¼ä¼ç¤¾
Power generation system and power generation system control device
JP2014089823A
( en )
2012-10-29
2014-05-15
Mitsubishi Heavy Ind Ltd
Combined cycle power generation system and operating method of combined cycle power generation system
Family Cites Families (6)
* Cited by examiner, â Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
JPH0656766B2
( en )
*
1985-01-29
1994-07-27
ä¸è±é»æ©æ ªå¼ä¼ç¤¾
Fuel cell device
JP3928319B2
( en )
*
2000-02-16
2007-06-13
æ¥ç£èªåè»æ ªå¼ä¼ç¤¾
Mobile fuel cell system
JP3614110B2
( en )
*
2001-02-21
2005-01-26
æ¥ç£èªåè»æ ªå¼ä¼ç¤¾
Fuel cell system
JP5293830B2
( en )
*
2009-10-07
2013-09-18
ãã¨ã¿èªåè»æ ªå¼ä¼ç¤¾
FUEL CELL SYSTEM AND METHOD FOR STOPPING FUEL CELL SYSTEM
EP2509144A1
( en )
*
2009-12-01
2012-10-10
Panasonic Corporation
Power generation system
JP6108872B2
( en )
*
2013-02-26
2017-04-05
ä¸è±æ¥ç«ãã¯ã¼ã·ã¹ãã ãºæ ªå¼ä¼ç¤¾
Combined power generation system, operation method, and control device
2014
2014-10-30
JP
JP2014221582A
patent/JP6472638B2/en
active
Active
2015
2015-10-27
US
US14/923,926
patent/US9666888B2/en
not_active
Expired - Fee Related
Patent Citations (5)
* Cited by examiner, â Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US6413662B1
( en )
*
2000-02-22
2002-07-02
General Motors Corporation
Fuel cell system shutdown with anode pressure control
US20070166598A1
( en )
2003-06-25
2007-07-19
Hydrogenics Corporation
Passive electrode blanketing in a fuel cell
JP4772470B2
( en )
2005-11-22
2011-09-14
ä¸è±é»æ©æ ªå¼ä¼ç¤¾
Fuel cell system
JP5446184B2
( en )
2008-09-12
2014-03-19
ã«ã·ãªè¨ç®æ©æ ªå¼ä¼ç¤¾
Power generation system and power generation system control device
JP2014089823A
( en )
2012-10-29
2014-05-15
Mitsubishi Heavy Ind Ltd
Combined cycle power generation system and operating method of combined cycle power generation system
Cited By (33)
* Cited by examiner, â Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US10724432B2
( en )
2017-11-07
2020-07-28
General Electric Company
Integrated fuel cell and engine combustor assembly
US11239470B2
( en )
2018-12-17
2022-02-01
General Electric Company
Integrated fuel cell and combustion system
US12374696B2
( en )
2018-12-17
2025-07-29
General Electric Company
Integrated fuel cell and combustion system
US12202616B2
( en )
2021-11-04
2025-01-21
General Electric Company
Relight of a propulsion system with a fuel cell
US11719441B2
( en )
2022-01-04
2023-08-08
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US11794912B2
( en )
2022-01-04
2023-10-24
General Electric Company
Systems and methods for reducing emissions with a fuel cell
US12123361B2
( en )
2022-01-04
2024-10-22
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US11933216B2
( en )
2022-01-04
2024-03-19
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US12037952B2
( en )
2022-01-04
2024-07-16
General Electric Company
Systems and methods for providing output products to a combustion chamber of a gas turbine engine
US11970282B2
( en )
2022-01-05
2024-04-30
General Electric Company
Aircraft thrust management with a fuel cell
US12034298B2
( en )
2022-01-10
2024-07-09
General Electric Company
Power source for an aircraft
US12074350B2
( en )
2022-01-21
2024-08-27
General Electric Company
Solid oxide fuel cell assembly
US12037124B2
( en )
2022-01-21
2024-07-16
General Electric Company
Systems and method of operating a fuel cell assembly
US12351329B2
( en )
2022-01-21
2025-07-08
General Electric Company
Systems and method of operating a fuel cell assembly
US12573647B2
( en )
2022-01-21
2026-03-10
General Electric Company
Solid oxide fuel cell assembly
US11804607B2
( en )
2022-01-21
2023-10-31
General Electric Company
Cooling of a fuel cell assembly
US11967743B2
( en )
2022-02-21
2024-04-23
General Electric Company
Modular fuel cell assembly
US12129789B2
( en )
2022-02-21
2024-10-29
General Electric Company
Systems and method of operating a fuel cell assembly, a gas turbine engine, or both
US12170390B2
( en )
2022-02-21
2024-12-17
General Electric Company
Systems and method of operating a fuel cell assembly, a gas turbine engine, or both
US12025061B2
( en )
2022-04-04
2024-07-02
General Electric Company
Gas turbine engine with fuel cell assembly
US12412914B2
( en )
2022-05-16
2025-09-09
General Electric Company
Environmental control system having a fuel cell assembly
US12428164B2
( en )
2022-05-16
2025-09-30
General Electric Company
Environmental control system having a fuel cell assembly
US12043406B2
( en )
2022-05-27
2024-07-23
General Electric Company
Method of operating a fuel cell assembly for an aircraft
US11817700B1
( en )
2022-07-20
2023-11-14
General Electric Company
Decentralized electrical power allocation system
US12301002B2
( en )
2022-08-26
2025-05-13
General Electric Company
Power dispatch control system for multiple power generation sources
US12078350B2
( en )
2022-11-10
2024-09-03
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US12240613B2
( en )
2022-11-10
2025-03-04
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US11859820B1
( en )
2022-11-10
2024-01-02
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US12567595B2
( en )
2022-11-10
2026-03-03
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US11923586B1
( en )
2022-11-10
2024-03-05
General Electric Company
Gas turbine combustion section having an integrated fuel cell assembly
US12270340B2
( en )
2023-02-23
2025-04-08
General Electric Company
Gas turbine engine and fuel cell assembly
US12261334B2
( en )
2023-02-23
2025-03-25
General Electric Company
Gas turbine engine and fuel cell assembly
US12584445B2
( en )
2023-02-23
2026-03-24
General Electric Company
Gas turbine engine and fuel cell assembly
Also Published As
Publication number
Publication date
JP6472638B2
( en )
2019-02-20
US20160126570A1
( en )
2016-05-05
JP2016091644A
( en )
2016-05-23
Similar Documents
Publication
Publication Date
Title
US20160126570A1
( en )
2016-05-05
Combined power generation system and unit, method, and program for controlling the same
US11437634B2
( en )
2022-09-06
Fuel cell system, hybrid power generation system, and control method for fuel cell system
US10141586B2
( en )
2018-11-27
Fuel cell module, combined power generation system including the same, and temperature control method of fuel cell power generation section
EP3605694A1
( en )
2020-02-05
Electrochemical element, electrochemical module, electrochemical device, energy system, solid oxide fuel cell, and method for producing electrochemical element
US20230411648A1
( en )
2023-12-21
Fuel cell power generation system
JP6494981B2
( en )
2019-04-03
Solid oxide fuel cell system, combined power generation system including the same, and method for stopping solid oxide fuel cell system
KR20220034198A
( en )
2022-03-17
Fuel cell system and its control method
US12046779B2
( en )
2024-07-23
Fuel cell power generation system for treating exhaust fuel gas
JP2018006004A
( en )
2018-01-11
Control device and control method of fuel cell, and power generating system
JP2018088324A
( en )
2018-06-07
Control device for hybrid power generation system, hybrid power generation system, control method for hybrid power generation system and control program for hybrid power generation system
JP2018032472A
( en )
2018-03-01
Fuel cell system and control method thereof, and power generation system and control method thereof
JP2018006005A
( en )
2018-01-11
Control device and control method of fuel cell, and power generating system
US20230395832A1
( en )
2023-12-07
Fuel cell power generation system and control method of fuel cell power generation system
JP6486649B2
( en )
2019-03-20
Combined power generation system and control method of combined power generation system
JP6239229B2
( en )
2017-11-29
Fuel cell system and fuel cell operating method
JP2016091816A
( en )
2016-05-23
Control device and method, and program for hybrid power generation system, and hybrid power generation system with the same
US20230395830A1
( en )
2023-12-07
Fuel cell power generation system and control method for fuel cell power generation system
JP2024106827A
( en )
2024-08-08
Electrochemical cell system and method for operating the electrochemical cell system
US20230130879A1
( en )
2023-04-27
Fuel cell power generation system
JP2018028988A
( en )
2018-02-22
Power generation system and protection control method thereof
KR20220035237A
( en )
2022-03-21
Fuel cell system and its control method
US20250105317A1
( en )
2025-03-27
Fuel cell system and method of operating thereof using humidified ammonia fuel
JP2018006002A
( en )
2018-01-11
Control device and control method of fuel cell, and power generating system
KR20250105085A
( en )
2025-07-08
Fuel cell system and controlling method thereof
Caprio
2018
Preliminary design of a low temperature micro-SOFC unit for natural gas networks auxiliary systems
Legal Events
Date
Code
Title
Description
2015-10-27
AS
Assignment
Owner name : MITSUBISHI HITACHI POWER SYSTEMS, LTD., JAPAN
Free format text : ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NAGAI, TAKUMA;OZAWA, HIROYUKI;REEL/FRAME:036894/0250
Effective date : 20150916
2017-05-10
STCF
Information on status: patent grant
Free format text : PATENTED CASE
2020-09-29
MAFP
Maintenance fee payment
Free format text : PAYMENT OF MAINTENANCE FEE, 4TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1551); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY
Year of fee payment : 4
2021-01-13
AS
Assignment
Owner name : MITSUBISHI POWER, LTD., JAPAN
Free format text : CHANGE OF NAME;ASSIGNOR:MITSUBISHI HITACHI POWER SYSTEMS, LTD.;REEL/FRAME:054975/0438
Effective date : 20200901
2023-05-26
AS
Assignment
Owner name : MITSUBISHI POWER, LTD., JAPAN
Free format text : CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVING PATENT APPLICATION NUMBER 11921683 PREVIOUSLY RECORDED AT REEL: 054975 FRAME: 0438. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT;ASSIGNOR:MITSUBISHI HITACHI POWER SYSTEMS, LTD.;REEL/FRAME:063787/0867
<p itemprop="