Toward Polyoxometalate Nanoelectronics

[2602.03512] Toward Polyoxometalate Nanoelectronics Skip to main content Search Submit Donate Log in Search arXiv Press Enter to search · Advanced search Condensed Matter > Mesoscale and Nanoscale Physics arXiv:2602.03512 (cond-mat) [Submitted on 3 Feb 2026 ( v1 ), last revised 23 Jul 2026 (this version, v3)] Title: Toward Polyoxometalate Nanoelectronics Authors: Dominique Vuillaume , Anna Proust View a PDF of the paper titled Toward Polyoxometalate Nanoelectronics, by Dominique Vuillaume and Anna Proust View PDF Abstract: Polyoxometalates form a large family of molecular oxide clusters of the early transition metals with unique and tunable properties (multi-redox, thermal and chemical robustness, magnetic). We review more than 30 years of experimental research on the electron transport properties of polyoxometalates devices, from thin films and self-assembled monolayers down to single-molecule junctions. We focus on the relationship between the polyoxometalate structures (structural type, nature of metals and heteroatoms, role of the counterions, redox states, electrode linkers and functional ligands) and the electronic structures of the polyoxometalate-based devices (energy positions of the molecular orbitals, energy offset at the interfaces). Then, we critically discuss the performances of polyoxometalates in nanoelectronics devices: capacitance and resistive switching memories, spintronics, quantum bits and neuromorphic devices. We conclude with a discussion about pending issues and perspectives. Subjects: Mesoscale and Nanoscale Physics (cond-mat.mes-hall) Cite as: arXiv:2602.03512 [cond-mat.mes-hall] (or arXiv:2602.03512v3 [cond-mat.mes-hall] for this version) https://doi.org/10.48550/arXiv.2602.03512 Focus to learn more arXiv-issued DOI via DataCite Journal reference: Chem. Rev., 126 (15), 8599-8643 (2026) Related DOI : https://doi.org/10.1021/acs.chemrev.6c00120 Focus to learn more DOI(s) linking to related resources Submission history From: Dominique Vuillaume [ view email ] [v1] Tue, 3 Feb 2026 13:30:58 UTC (43,044 KB) [v2] Wed, 10 Jun 2026 13:11:14 UTC (10,472 KB) [v3] Thu, 23 Jul 2026 08:53:01 UTC (10,993 KB) Full-text links: Access Paper: View a PDF of the paper titled Toward Polyoxometalate Nanoelectronics, by Dominique Vuillaume and Anna Proust View PDF view license Current browse context: cond-mat.mes-hall < prev | next > new | recent | 2026-02 Change to browse by: cond-mat References & Citations NASA ADS Google Scholar Semantic Scholar export BibTeX citation Loading... BibTeX formatted citation × loading... Data provided by: Bookmark Bibliographic Tools Bibliographic and Citation Tools Bibliographic Explorer Toggle Bibliographic Explorer ( What is the Explorer? ) Connected Papers Toggle Connected Papers ( What is Connected Papers? ) Litmaps Toggle Litmaps ( What is Litmaps? ) scite.ai Toggle scite Smart Citations ( What are Smart Citations? ) Code, Data, Media Code, Data and Media Associated with this Article alphaXiv Toggle alphaXiv ( What is alphaXiv? ) Links to Code Toggle CatalyzeX Code Finder for Papers ( What is CatalyzeX? ) DagsHub Toggle DagsHub ( What is DagsHub? ) GotitPub Toggle Gotit.pub ( What is GotitPub? ) Huggingface Toggle Hugging Face ( What is Huggingface? ) ScienceCast Toggle ScienceCast ( What is ScienceCast? ) Demos Demos Replicate Toggle Replicate ( What is Replicate? ) Spaces Toggle Hugging Face Spaces ( What is Spaces? ) Spaces Toggle TXYZ.AI ( What is TXYZ.AI? ) Related Papers Recommenders and Search Tools Link to Influence Flower Influence Flower ( What are Influence Flowers? ) Core recommender toggle CORE Recommender ( What is CORE? ) IArxiv recommender toggle IArxiv Recommender ( What is IArxiv? ) Author Venue Institution Topic About arXivLabs arXivLabs: experimental projects with community collaborators arXivLabs is a framework that allows collaborators to develop and share new arXiv features directly on our website. Both individuals and organizations that work with arXivLabs have embraced and accepted our values of openness, community, excellence, and user data privacy. arXiv is committed to these values and only works with partners that adhere to them. Have an idea for a project that will add value for arXiv's community? Learn more about arXivLabs . Which authors of this paper are endorsers? | Disable MathJax ( What is MathJax? ) We gratefully acknowledge support from our major funders , member institutions , , and all contributors. About · Help · Contact · Subscribe · Copyright · Privacy · Accessibility · Operational Status (opens in new tab) Major funding support from

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