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Regioselective Biosynthesis Of Reveromycin Derivatives By Cytochrome P450revi Mutant In Actinacidiphila Reveromycinica Sn-593
Reveromycin A (RM-A) (1) has a 6,6-spiroacetal core structure that is important for its biological activity. However, 1 undergoes a spiroacetal rearrangement to form RM-B (2) with a 5,6-spiroacetal core, which exhibits reduced bioactivity. This undesired rearrangement is partly due to the hemisuccin
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