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d'Q = TdS for Infinitesimal Irreversible Processes: On the Differential Form of the Clausius Inequality
Conventionally, the differential form of the Clausius inequality is adopted for infinitesimal irreversible processes. We show that the correct first-order form for infinitesimal quasi-static irreversible processes is the equality d'Q=TdS rather than d'Q < TdS. This provides a purely thermodynamic pr
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