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Syntheses, crystal structures, magnetic properties and vibrational spectra of nitridoborate-halide compounds Sr-2[BN2]Br and Eu-2[BN2]X (X = Br, I) with isolated [BN2](3-) units
The title compounds Sr-2[BN2]Br (1), Eu-2[BN2]Br (2) and Eu-2[BN2]I (3) were obtained from reactions of mixtures of Sr-3[BN2](2) and SrBr2 (1) and the binaries EuN, h-BN and EuX2 (X = Br, I) (2, 3), respectively. The crystal structure of Sr-2[BN2]Br was solved from X-ray powder diffraction data and
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