Repositorio de Universidad Autónoma de Chile.
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Gold(i) ethylene complexes supported by electron-rich scorpionates
Ethylene complexes of gold(i) have been stabilized by electron-rich, κ2-bound tris(pyrazolyl)borate ligands. Large up-field shifts of olefinic carbon NMR resonances and relatively long C distances of gold bound ethylene are indicative of significant Au(i) → ethylene π-backbonding relative to the ana
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