Repositorio de Universidad Autónoma de Chile.
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Triple 1D1D superatomic bonding. Au22(dppo)6 as a Π4- And Δ2-triply bonded cluster based on Au11 assembled units
δ-Bonds have been intimately related to metal-metal bonds of d-elements since the archetypal d4-d4 [Re2Cl8]2- ion with a σ2π4δ2 bond. Currently, the notion of multiple superatom arrangements as initial steps toward molecular materials within the building-up approach is dominated by P-shell character
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