Repositorio de Universidad Autónoma de Chile.
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Eclipsed- and Staggered-[Ge18Pd3{EiPr3}6]2- (E = Si, Sn): Positional Isomerism in Deltahedral Zintl Clusters
We report the synthesis and characterization of the cluster anions [Ge18Pd3{SiiPr3}6]2- (1) with a core of face-fused twinned icosahedra, Ge18Pd3, and two sets of three iPr3Si-substituents positioned in "eclipsed" geometry. The new anion is a positional isomer of the recently reported "staggered" st
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