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Water, vacancies, and competing exchange interactions in Prussian blue analogues: a neutron diffraction study of field and dehydration-driven magnetic transitions
We report a neutron diffraction study of the structural and magnetic properties of a family of ferro- and ferrimagnetic Prussian blue analogues (PBAs), $A_4$[Fe(CN)$_6$]$_{2.7}$ ($A$ = Co, Mn, Ni), Rb$_2$Ni$_4$[Fe(CN)$_6$]$_{3.3}$, and Mn$_4$[Cr(CN)$_6$]$_{2.7}$, as a function of temperature (2--450
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