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Beyond the Pre‐Equilibrium Approximation: Consequences of Elementary Step (Ir)reversibility on the Mechanistic Interpretation of Tafel Slope
The relationship between electrochemical potential and reaction rate-or Tafel slope-is fundamental to the study of multi-step charge transfer reactions. However, despite its importance and ubiquitous use, Tafel slope is seldom interpreted outside of "cardinal" values. The mechanistic interpretation
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