HAL (France)
open access
Sulfur‐to‐Metal Single‐Atom Editing of a Thiourea Self‐Assembled Monolayer into an Adatom‐Bound N‐Heterocyclic Carbene Monolayer on Coinage Metal Surfaces
ABSTRACT N‐Heterocyclic carbene (NHC) self‐assembled monolayers (SAMs) are emerging as robust and versatile surface ligands, yet their direct on‐surface construction with atomic precision remains elusive. Here, we report a reagent‐free, thermally driven on‐surface strategy for single‐atom editing, p
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